Calories (nutritional)
A nutritional calorie, specifically a kilocalorie (kcal), is the amount of energy required to raise the temperature of one kilogram of water by one degree Celsius. In nutritional contexts, the term "calorie" typically refers to a kilocalorie.
Btu (3.9°C)
The Btu (3.9°C) is defined as the amount of heat required to raise the temperature of one pound of water by one degree Fahrenheit at the temperature where water reaches its maximum density which occurs at approximately 3.9°C (39°F).