Calories (nutritional)
A nutritional calorie, specifically a kilocalorie (kcal), is the amount of energy required to raise the temperature of one kilogram of water by one degree Celsius. In nutritional contexts, the term "calorie" typically refers to a kilocalorie.
Btu (15.6°C)
The Btu (15.6°C) specifically refers to the energy needed to raise the temperature of water from 60°F (15.6°C) to 61°F.