Calories (mean)
A mean calorie is a unit of energy that was historically used to quantify the amount of energy required to raise the temperature of one gram of water by one degree Celsius, approximately equal to 4.184 joules.
Btu (15.6°C)
The Btu (15.6°C) specifically refers to the energy needed to raise the temperature of water from 60°F (15.6°C) to 61°F.