Btu (3.9°C)
The Btu (3.9°C) is defined as the amount of heat required to raise the temperature of one pound of water by one degree Fahrenheit at the temperature where water reaches its maximum density which occurs at approximately 3.9°C (39°F).
Calories (15°C,CIPM, 1950)
The calorie defined as CIPM, 1950 or the "15°C calorie" is a unit of energy that was historically used to quantify the amount of heat required to raise the temperature of one gram of water by one degree Celsius at 15°C. This definition was established by the International Committee for Weights and Measures (CIPM) in 1950.