Btu (15.6°C)
The Btu (15.6°C) specifically refers to the energy needed to raise the temperature of water from 60°F (15.6°C) to 61°F.
Calories (Kilogram,I.T.)
The kilogram calorie is often referred to as the kilocalorie or Calorie with an uppercase 'C'). It is defined as the amount of energy required to raise the temperature of one kilogram of water by one degree Celsius at one atmosphere of pressure.