Btu (15.6°C)
The Btu (15.6°C) specifically refers to the energy needed to raise the temperature of water from 60°F (15.6°C) to 61°F.
Calories (20°C)
A Calorie (20°C) is sometimes referred to as a small calorie or gram calorie. It is a unit of energy defined as the amount of heat required to raise the temperature of one gram of water by one degree Celsius from 19.5°C to 20.5°C.